Product ID:PT 230 TRI-DIE
MSDS Date:09/19/1991
FSC:6850
NIIN:00N011288
MSDS Number: CCVXT

WHITMIRE RESEARCH LABORATORIES INC

9568 TREE COURT IND BLVD
ST LOUIS, MO 63122
US

Emergency Phone: 314-576-0120;800-424-9300(CHEMTREC)

Info Phone: 314-255-5371

Preparer: MICHAEL G SARLI

Cage: 67184

WHITMIRE MICRO GEN RESEARCH LABORATORIES, INC.

ST LOUIS, MO 63122-6620 US

Telephone: 636-225-5371

Cage: 67184

SOLVENTS (AND INGREDIENT 2)

Fraction By Weight: 87.0%

OSHA PEL N/K

ACGIH TLV: N/K

PROPELLANTS

OSHA PEL N/K

ACGIH TLV: N/K

ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 57%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANE, CHLORODIFLUORO-; (MONOCHLORODIFLUOROMETHANE) (SARA

CAS: 75-45-6

RTECS: PA6390000

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

PYRETHRUM; (PYRETHRINS) (CERCLA)

CAS: 8003-34-7

RTECS: UR4200000

Fraction By Weight: 0.3%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TOLUENE, ALPHA-(2-(2-BUTOXYETHOXY)ETHOXY)-4,5-

CAS: 51-03-6

RTECS: XS8050000

Fraction By Weight: 3.0%

OSHA PEL N/K

ACGIH TLV: N/K

SILICA GEL

CAS: 1343-98-2

Fraction By Weight: 4.0%

OSHA PEL 6 MG/M3

ACGIH TLV: 10 MG/M3

MINERAL SPIRITS; (ISOPARAFFINIC PETROLEUM SOLVENT)

CAS: 64475-85-0

RTECS: PY8240000

Fraction By Weight: 5.7%

OSHA PEL 500 PPM (MFR)

ACGIH TLV: N/K

LD50 LC50 Mixture:LD50(ORAL,RAT):>5,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGEST & INHAL:UNLIKELY DUE TO PROD
BEING PRESS PROD & PRDCING PARTICLES LG ENOUGH NOT TO BE RESP. FEW
CASES OF EXTRINSIC ASTHMA FROM PYRETHRIN MIXS HAVE BEEN RPTD.
PRLNGD EXPOS MAY CAUSE DRYING OF NO SE & THROAT. MIN
ANESTHETIC/NARCOTIC EFTS MAY BE SEEN IN RANGE OF 500-1000 PPM
1,1,1-TRICHLOROETHANE. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:. WHEN USED ACCORD TO LBL DIRECTIONS
THIS LEVEL WILL NOT BE ATTAINED. CHLOROFLUOROCARB (CFC) &
CHLOROCARBON MATLS HAVE PRDCED SENSIT OF MYOCARDIUM TO EPINEPHRINE
IN LAB ANIMALS & COULD HAVE SIMILAR ET IN HUMANS. ADRENOMIMETICS
(I.E., EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT FOR
LIFE-SUSTAINING (SUPDAT)
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:EYES:FLUSH W/PLENTY OF WATER FOR @ LST 15 MIN. SEEK MED ATTN.
INGEST:CALL MD/POIS CTL CTR IMMED. GASTRIC LAVAGE MAY BE INDICATED.
DO NOT INDUCE VOMIT. VOMIT MAY CAUSE ASPIR PNEUM. TREATMENT IS
SYMPTOM ATIC. ANTIHISTAMINES ARE OF VALUE. INHAL:REMOVE TO FRESH
AIR. APPLY ARTF RESP IF INDICATED. SKIN:REMOVE CONTAM CLTHG & WASH
AFFECTED AREA W/SOAP & WATER. SEEK MED ATTN IF IRRIT PERSISTS.

Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESSURE. EXPOSURE TO
TEMPERATURES ABOVE 130F MAY CAUSE BURSTING. THERMAL DECOMP PRODS
MAY INCLUDE PHOSGENE, FLUORIDES & CHLORIDES .

Spill Release Procedures:IF CNTNR BEGINS TO LEAK (THROUGH PUNCTURE,
ETC) ALLOW IT TO DISCHARGE COMPLETELY IN WELL VENTD AREA, THEN DISP
IN SAFE PLACE. IN CASE OF SPILLAGE ON SKIN, WASH THORO W/SOAP &
WATER. EMER PHONE # OF CH EMTREC (800) 424-9300 (FOR TRANSPORTATION
SPILLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTENTS UNDER PRESS. DO NOT PUNCTURE.
DO NOT STORE NEAR HEAT/OPEN FLAME. DO NOT REMAIN IN TREATED AREAS.
EXPOS TO TEMP >130F MAY CAUSE BURSTING.
Other Precautions:AVOID SKIN CONT. FOODS/EATING UTENSILS SHOULD BE
REMOVED/COVERED DURING TREATMENT. REMOVE PETS, BIRDS & COVER FISH
BOWLS DURING TREATMENT. VENT AREA AFTER TREATMENT IS COMPLETED. NO
SMKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF (SUPDAT)

Respiratory Protection:NONE REQUIRED IF APPLIED ACCORDING TO LABEL
DIRECTIONS. PROLONGED EXPOSURE OR WHEN EXPOSURE GUIDELINES
EXCEEDED, USE A NIOSH APPROVED PESTICIDE DUST RESPIRATOR.
Ventilation:LOC EXHST, MECHANICAL, SPECIAL:NONE REQUIRED. OTHER:PROVIDE
ADEQUATE VENTILATION OF TREATMENT AREA.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . NONE REQUIRED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CFC'S
& CHLOROCARBONS . OTHER PRECS:ARC WELDING, OPEN FLAMES OR HOT
SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF
CHLORIDES, FLUORIDES OR PHOSGENE .

Vapor Pres:65PSIG@70F
Spec Gravity:0.90 (H*2O=1)
Appearance and Odor:SPRAYS AS TAN POWDER WITH A CHARACTERISTIC
PYRETHRUM ODOR.
Percent Volatiles by Volume:93.7

Stability Indicator/Materials to Avoid:NO
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:INEFINITE WHEN USED ACCORDING TO
DIRECTIONS. DO NOT SPRAY INTO OPEN FLAME OR ONTO VERY HOT SURFACES.
Hazardous Decomposition Products:THERMAL DECOMP IN OPEN FLAME MAY RSLT
IN HALOGEN ACIDS & CARBON DIOXIDE. CHLORIDES, FLUORIDES & PHOSGENE
.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . AEROSOL CYLINDER IS NOT REFILLABLE. DO NOT ATTEMPT TO
RECHARGE. WHEN CYLINDER IS EXHAUSTED, DISCARD IN SAFE PLACE. DO NOT
THROW INTO F IRE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.